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31.
《International Journal of Hydrogen Energy》2022,47(78):33403-33409
The 3D geometry of a hydrogen absorbing metal grain (Pd) is mimicked by a membrane made of the metal with identical properties, which is sealed on one side with a hydrogen semi-impermeable surface (Cu). The hydrogen loss through the sealed membrane surface is negligible, i.e., the hydrogen uptake measurement is that of a bulk material (Sieverts measurement), but the surface desorbs sufficient hydrogen to be detected by a mass spectrometer. With this, two independent spatial and temporal kinetic properties are defined which allow the reconstruction of the time dependent hydrogen distribution inside the membrane. As proof of concept, the mechanism of hydride formation in Pd is analyzed, corroborating the formation and growth of incoherent interfaces during hydrogen sorption. 相似文献
32.
The development of efficient filters is an essential part of industrial machinery design, specifically to increase the lifespan of a machine. In the filter chamber design considered in this study, the magnetic material is placed along the horizontal surface of the filter chamber. The inside of the filter chamber is layered with a porous material to restrict the outflow of unwanted particles. This study aims to investigate the flow, pressure, and heat distribution in a dilating or contracting filter chamber with two outlets driven by injection through a permeable surface. The proposed model of the fluid dynamics within the filter chamber follows the conservation equations in the form of partial differential equations. The model equations are further reduced to a steady case through Lie's symmetry group of transformation. They are then solved using a multivariate spectral-based quasilinearization method on the Chebyshev–Gauss–Lobatto nodes. Insights and analyses of the thermophysical parameters that drive optimal outflow during the filtration process are provided through the graphs of the numerical solutions of the differential equations. We find, among other results, that expansion of the filter chamber leads to an overall decrease in internal pressure and an increase in heat distribution inside the filter chamber. The results also show that shrinking the filter chamber increases the internal momentum inside the filter, which leads to more outflow of filtrates. 相似文献
33.
This article addresses an investigation of the entropy analysis of Williamson nanofluid flow in the presence of gyrotactic microorganisms by considering variable viscosity and thermal conductivity over a convectively heated bidirectionally stretchable surface. Heat and mass transfer phenomena have been incorporated by taking into account the thermal radiation, heat source or sink, viscous dissipation, Brownian motion, and thermophoretic effects. The representing equations are nonlinear coupled partial differential equations and these equations are shaped into a set of ordinary differential equations via a suitable similarity transformation. The arising set of ordinary differential equations was then worked out by adopting a well-known scheme, namely the shooting method along with the Runge-Kutta-Felberge integration technique. The effects of flow and heat transfer controlling parameters on the solution variables are depicted and analyzed through the graphical presentation. The survey finds that magnifying viscosity parameter, Weissenberg number representing the non-Newtonian Williamson parameter cause to retard the velocity field in both the directions and thermal conductivity parameter causes to reduce fluid temperature. The study also recognizes that enhancing magnetic parameters and thermal conductivity parameters slow down the heat transfer rate. The entropy production of the system is estimated through the Bejan number. It is noticeable that the Bejan number is eminently dependent on the heat generation parameter, thermal radiation parameter, viscosity parameter, thermal conductivity parameter, and Biot number. The skillful accomplishment of the present heat and mass transfer system is achieved through the exteriorized choice of the pertinent parameters. 相似文献
34.
Higher transmission rate is one of the technological features of prominently used wireless communication namely Multiple Input Multiple Output-Orthogonal Frequency Division Multiplexing (MIMO–OFDM). One among an effective solution for channel estimation in wireless communication system, specifically in different environments is Deep Learning (DL) method. This research greatly utilizes channel estimator on the basis of Convolutional Neural Network Auto Encoder (CNNAE) classifier for MIMO-OFDM systems. A CNNAE classifier is one among Deep Learning (DL) algorithm, in which video signal is fed as input by allotting significant learnable weights and biases in various aspects/objects for video signal and capable of differentiating from one another. Improved performances are achieved by using CNNAE based channel estimation, in which extension is done for channel selection as well as achieve enhanced performances numerically, when compared with conventional estimators in quite a lot of scenarios. Considering reduction in number of parameters involved and re-usability of weights, CNNAE based channel estimation is quite suitable and properly fits to the video signal. CNNAE classifier weights updation are done with minimized Signal to Noise Ratio (SNR), Bit Error Rate (BER) and Mean Square Error (MSE). 相似文献
35.
《International Journal of Hydrogen Energy》2022,47(25):12569-12581
Heteroatomic doping is an effective way to optimize the electronic structure of carbon nitride to boost photocatalytic performance. However, the extra introduced defects could result in the decrease of its crystallinity. In this work, crystalline K–I co-doped carbon nitride (K–I–CCN) was simply synthesized from molten salt ionthermal post-calcination in nitrogen atmosphere. Structure characterization results indicate that compared to K–CCN synthesized from conventional molten salt heat treatment in air, nitrogen heating atmosphere is more conductive for the formation of homogeneous pore structure of the catalyst, which has larger surface area and pore volume, while could repairing some defects and resulting in better polymerization crystallization. In addition, except the implanting of K, I doping is still retained after nitrogen heat treatment, thus forming K–I co-doping structure. Due to the positive charge effect of K–I co-doping, K–I–CCN has a narrower band gap, higher surface charge density and stronger charge transport, so it performs significantly enhanced photocatalytic H2 evolution activity from water splitting. 相似文献
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38.
Najiba Hasan Hamad 《亚洲传热研究》2022,51(5):3794-3814
Classical Fourier's theory is well-known in continuum physics and thermal sciences. However, the primary drawback of this law is that it contradicts the principle of causality. To explore the thermal relaxation time characteristic, Cattaneo–Christov's theory is adopted thermally. In this regard, the features of magnetohydrodynamic (MHD) mixed convective flows of Casson fluids over an impermeable irregular sheet are revealed numerically. In addition, the resulting system of partial differential equations is altered via practical transformations into nonlinear ordinary differential equations. An advanced numerical algorithm is developed in this respect to get higher approximations for temperature and velocity fields, as well as their corresponding wall gradients. For validating our numerical code, the current outcomes are compared with the available literature results. Moreover, it is revealed that the velocity field is more prominent in the suction flow situation as compared with the injection flow case. It is also found that the Casson fluid is hastened in the case of lower yield stress. Larger values of thermal relaxation parameters create a lessening trend in the temperature distribution and its related boundary layer breadth. 相似文献
39.
Koratagere Revanna Nagaraju Ulavathi Shettar Mahabaleshwar Muddenahalli Siddalinga Prasad Basma Souayeh 《亚洲传热研究》2022,51(6):5288-5301
This article focuses on analytic solutions for Newtonian fluid flow with slip and mass transpiration on a porous stretching sheet using the differential transform method and Pade approximants of an exceptionally nonlinear differential equation. The impacts of different parameters including mass transpiration (suction/injection), Navier's slip, and Darcy number parameters on the velocity of the liquid and tangential stress are discussed. A comprehensive comparison of our results with the previous one in the literature is made, and the results showed good agreement. An investigation is conducted of a combination of magnetic liquids that are conceivably pertinent for wound medicines, skin repair, and astute coatings for natural gadgets. It is found that there is a decrease in the velocity profiles and the boundary layer thickness for the case of suction. 相似文献
40.
《Ceramics International》2022,48(11):15056-15063
Hydrogen (H2) sensors based on metal oxide semiconductors (MOS) are promising for many applications such as a rocket propellant, industrial gas and the safety of storage. However, poor selectivity at low analyte concentrations, and independent response on high humidity limit the practical applications. Herein, we designed rGO-wrapped SnO2–Pd porous hollow spheres composite (SnO2–Pd@rGO) for high performance H2 sensor. The porous hollow structure was from the carbon sphere template. The rGO wrapping was via self-assembly of GO on SnO2-based spheres with subsequent thermal reduction in H2 ambient. This sensor exhibited excellently selective H2 sensing performances at 390 °C, linear response over a broad concentration range (0.1–1000 ppm) with recovery time of only 3 s, a high response of ~8 to 0.1 ppm H2 in a minute, and acceptable stability under high humidity conditions (e. g. 80%). The calculated detection limit of 16.5 ppb opened up the possibility of trace H2 monitoring. Furthermore, this sensor demonstrated certain response to H2 at the minimum concentration of 50 ppm at 130 °C. These performances mainly benefited from the special hollow porous structure with abundant heterojunctions, the catalysis of the doped-PdOx, the relative hydrophobic surface from rGO, and the deoxygenation after H2 reduction. 相似文献